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- Author(s):
- Bornschlegl, Alexander; Loge, Christoph; Boesl, Ulrich
- Title:
- Investigation of CD effects in the multi photon ionisation of R-(+)-3-methylcyclopentanone
- Abstract:
- The CD in ion yield for different excitation/ionization schemes for R-(+)-3-methylcyclopentanone was measured with CD laser mass spectrometry (CD-LAMS). The authors discovered a cumulative CD effect of successive electronic transitions, resulting in an enhancement of the CD in ion yield. Two photon excitation of the n-Ï€*-transition compared with the one photon process showed a vanishing CD effect. [on SciFinder(R)]
- Keywords:
- Circular dichroism Electronic transition Photoexcitation Photoionization mass spectra (CD effects in multi photon ionization of R-(+)-3-methylcyclopentanone) Photoionization (multiphoton CD effects in multi photon ionization of R-(+)-3-methylcyclopentanone) Photoexcitation (two-photon CD effects in multi photon ionization of R-(+)-3-methylcyclopentanone) CD multi photon ionization R methylcyclopentanone
- Congress title:
- CAN 148:64791 73-2 Optical, Electron, and Mass Spectroscopy and Other Related Properties Chemistry Department, Technical University Munich, Garching, Germany. Journal 0009-2614 6672-30-6 Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (CD effects in multi photon ionization of R-(+)-3-methylcyclopentanone)
- Journal title:
- Chem. Phys. Lett.
- Year:
- 2007
- Journal volume:
- 447
- Journal issue:
- 4-6
- Pages contribution:
- 187-191
- Fulltext / DOI:
- doi:10.1016/j.cplett.2007.09.012
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