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Document type:
Journal Article 
Author(s):
Zhao, C.; Camaioni, D. M.; Lercher, J. A. 
Title:
Selective catalytic hydroalkylation and deoxygenation of substituted phenols to bicycloalkanes 
Abstract:
Phenol and substituted phenols are hydroalkylated and hydrodeoxygenated to bi-cycloalkanes in a tandem reaction over Pd nanoclusters supported on a large-pore molecular sieve HBEA at 473-523 K using water as solvent. The HBEA-supported Pd catalyst (metal-acid ratio: 1:22 mol/mol) optimally balances the competing rates of metal catalyzed hydrogenation as well as of solid acid-catalyzed dehydration and carbon-carbon coupling to combine hydrodeoxygenation and dimerization of phenol derivatives to C...    »
 
Congress title:
ISI Document Delivery No.: 920VE Times Cited: 6 Cited Reference Count: 34 Zhao, Chen Camaioni, Donald M. Lercher, Johannes A. Kang, Zhai/G-8010-2012 Technische Universitat Munchen; US Department of Energy's (DOE) Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences This work was supported by Technische Universitat Munchen in the framework of the European Graduate School for Sustainable Energy. The authors thank Prof. Andreas Jentys (TU Munchen, Germany) pr...    »
 
Journal title:
Journal of Catalysis 
Year:
2012 
Journal volume:
288 
Pages contribution:
92-103