User: Guest  Login
Document type:
Journal Article 
Author(s):
Riener, K.; Hogerl, M. P.; Gigler, P.; Kuhn, F. E. 
Title:
Rhodium-Catalyzed Hydrosilylation of Ketones: Catalyst Development and Mechanistic Insights 
Abstract:
The current status of rhodium-catalyzed hydrosilylation of ketones is reviewed, focusing on development milestones leading to state of the art chiral ligand systems and mechanistic understanding. Four ligand classes are discussed: phosphorus-, nitrogen-, mixed-donor ligand- as well as N-heterocyclic carbene-based ligand systems. Results relevant for a mechanistic understanding of the reaction are presented, starting from the initial investigations by Ojima, limitations of the first mechanistic p...    »
 
Congress title:
ISI Document Delivery No.: 920FG Times Cited: 4 Cited Reference Count: 102 Riener, Korbinian Hoegerl, Manuel P. Gigler, Peter Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010 Wacker Chemie AG We are grateful for financial support of the Wacker Chemie AG (Ph.D. grants for M.P.H. and P.G.). 4 Amer chemical soc Washington 
Journal title:
Acs Catalysis 
Year:
2012 
Journal volume:
Journal issue:
Pages contribution:
613-621 
Fulltext / DOI: