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Document type:
Journal Article
Author(s):
Voss, F.; Vogt, F.; Herdtweck, E.; Bach, T.
Title:
Synthesis of Catalytically Active Ruthenium Complexes with a Remote Chiral Lactam as Hydrogen-Bonding Motif
Abstract:
A terminal alkyne was prepared, which is linked by a carbon-carbon bond to a conformationally restricted, U-shaped chiral lactam, that is, more precisely, to carbon atom C7 of 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one. The alkyne was connected to various ligands (bipyridine, terpyridine, pybox) by Sonogashira cross-coupling with the respective bromides or triflates. The resulting products were converted into four defined ruthenium complexes (58-94
Congress title:
ISI Document Delivery No.: 730YS Times Cited: 1 Cited Reference Count: 61 Voss, Felix Vogt, Florian Herdtweck, Eberhardt Bach, Thorsten Deutsche Forschungsgemeinschaft; Fonds der Chemischen Industrie Our research was supported by the Deutsche Forschungsgemeinschaft (Schwerpunktprogramm 1179 Organokatalyse) and by the Fonds der Chemischen Industrie (Ph.D. scholarship to Fl.V.). 1 Georg thieme verlag kg Stuttgart
Journal title:
Synthesis-Stuttgart
Year:
2011
Journal issue:
6
Pages contribution:
961-971
Fulltext / DOI:
doi:10.1055/s-0030-1258424
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