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Document type:
Journal Article 
Author(s):
Diebl, B. E.; Yeong, H. Y.; Cokoja, M.; Herdtweck, E.; Voit, B.; Kuhn, F. E. 
Title:
Synthesis and catalytic application of monometallic molybdenum(IV) nitrile complexes 
Abstract:
The novel molybdenum(IV) compound [MoO(NCMe)(5)][B(C(6)E(5))(4)](2) (1a) has been prepared by air oxidation of [Mo(CO)(3)(NCMe)(3)] in the presence of [H(OEt(2))(2)][B(C(6)F(5))(4)] at room temperature. The [MoO(NCMe)(5)](2+) cation shows a distorted octahedral configuration with two different acetonitrile-metal bond lengths due to a trans effect of the oxo-ligand. The trans-acetonitrile ligand is easily abstracted under oil pump vacuum to form [MoO(NCMe)(4)][B(C(6)F(5))(4)](2) (1b). The complex...    »
 
Congress title:
ISI Document Delivery No.: 725FN Times Cited: 3 Cited Reference Count: 25 Diebl, Bernd E. Yeong, Hui Yee Cokoja, Mirza Herdtweck, Eberhardt Voit, Brigitte Kuehn, Fritz E. Cokoja, Mirza/B-6906-2009; Voit, Brigitte/D-4755-2009; Kuhn, Fritz/A-3113-2010 BASF SE, Ludwigshafen This work was supported by BASF SE, Ludwigshafen. S. F. Rach and C. E. Fischer are acknowledged for proof reading of the manuscript. Professor Dr. Janos Mink (Hungarian Academy of Sciences) is also acknowledged for valuable di...    »
 
Journal title:
Tetrahedron Letters 
Year:
2011 
Journal volume:
52 
Journal issue:
Pages contribution:
955-959