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Author(s):
Tschurl, Martin; Boesl, Ulrich 
Title:
Photodetachment-photoelectron spectroscopy of jet-cooled chrysene 
Abstract:
Jet-cooled chrysene anions have been produced by attachment of slow laser-induced photoelectrons. The mols. have been studied by photodetachment-photoelectron spectroscopy using various wavelengths of the detachment laser. The adiabatic electron affinity of chrysene was directly detd. to be 0.32 ± 0.01 eV. In the S0 state of neutral chrysene two different vibrational modes are visible. Both are assigned to breathing modes of the arom. ring system. In addn., the first excited triplet state is obs...    »
 
Keywords:
Electron affinity (adiabatic photodetachment-photoelectron spectroscopy of jet-cooled chrysene) Electron attachment Electron photodetachment Photoelectron spectra Singlet-triplet splitting (photodetachment-photoelectron spectroscopy of jet-cooled chrysene) chrysene photodetachment photoelectron spectra electron affinity 
Congress title:
CAN 144:476922 73-6 Optical, Electron, and Mass Spectroscopy and Other Related Properties Department Chemie, Technische Universitaet Muenchen, Garching, Germany. Journal 1387-3806 218-01-9 (Chrysene) Role: PRP (Properties) (photodetachment-photoelectron spectroscopy of jet-cooled chrysene) 
Journal title:
Int. J. Mass Spectrom. 
Year:
2006 
Journal volume:
249/250 
Pages contribution:
364-369