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- Document type:
- Zeitschriftenaufsatz
- Author(s):
- Tschurl, Martin; Boesl, Ulrich
- Title:
- IR-photodissociation and photodetachment spectroscopy of Cl− · (NH3)x (IR:
- Abstract:
- Complexes of ammonia mols. and one chloride ion have been studied by photodetachment and IR-photodissocn. spectroscopy. For the smallest anionic complex, the stabilization energy with respect to the bare chloride ion and vibrational frequencies have been detd. Two bands showed a splitting due to rotational branches, which could be represented by simulation. Rotational consts. obtained by former ab initio calcns. are confirmed and rotational consts. of a vibrationally excited state are supplied.... »
- Keywords:
- Cluster structure Electron photodetachment Excited vibrational state IR photolysis IR spectra Molecular rotation Stabilization energy Vibrational excitation Vibrational excitation Vibrational frequency (IR-photodissocn. and photodetachment spectroscopy of Cl--NH3 clusters) chloride ammonia cluster IR photodissocn photodetachment spectroscopy IR spectra rotational const chloride ammonia cluster
- Congress title:
- CAN 149:139578 74-1 Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes Technical University of Munich, Chemistry Department, Garching, Germany. Journal 0009-2614 152309-82-5; 1036357-29-5; 1036357-32-0; 1036357-34-2 Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (IR-photodissocn. and photodetachment spectroscopy of Cl--NH3 clusters)
- Journal title:
- Chem. Phys. Lett.
- Year:
- 2008
- Journal volume:
- 456
- Journal issue:
- 4-6
- Pages contribution:
- 150-155
- Fulltext / DOI:
- doi:10.1016/j.cplett.2008.03.041
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