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Author(s):
Boesl, Ulrich; Distelrath, Volker; Selzle, Heinrich 
Title:
The weakly-bound complex Cl.N2O studied by high resolution photodetachment photoelectron spectroscopy 
Abstract:
Zero kinetic energy photoelectron spectroscopy of the weakly bound complex Cl(-).N(2)O is presented. Adiabatic detachment energies between the anionic complex and the neutral complex states X(1/2), I(3/2), and II(1/2) as well as frequencies of van der Waals modes are supplied. Supported by theoretical simulations, these results correlate with a T-shaped structure of the anionic and an L-shaped structure of the neutral molecular complex. The weakly bound neutral complex Cl.N(2)O has been discusse...    »
 
Keywords:
Anions *Chlorides: CH, chemistry Electrons Hydrogen Bonding Kinetics Mathematics Models, Molecular *Nitrogen Oxides: CH, chemistry *Nitrous Oxide: CH, chemistry Spectrum Analysis Thermodynamics 0 (Anions) 0 (Chlorides) 0 (Nitrogen Oxides) 
Congress title:
Physical Chemistry, Chemistry Department, Technical University Munich, Garching, Germany. 1463-9076 FIELD Electronic Internat.Standard Doc. Number: England: United Kingdom Journal; Article; (JOURNAL ARTICLE) 10024-97-2 (Nitrous Oxide) 
Journal title:
Phys Chem Chem Phys 
Year:
2008 
Journal volume:
10 
Journal issue:
41 
Pages contribution:
6252-7 
Fulltext / DOI:
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