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Document type:
Zeitschriftenaufsatz 
Author(s):
Jandl, Christian; Pöthig, Alexander 
Title:
A hybrid carbocyclic/N-heterocyclic carbene ligand 
Abstract:
We report the synthesis and characterisation of the first complex bearing a bidentate carbocyclic/N-heterocyclic carbene ligand, which represents an unprecedented combination of these two carbene classes. Starting from an unsubstituted cycloheptatrienylidene-Pd complex, the ligand was built up in an on-site synthesis at the metal center. DFT calculations were employed to understand the crucial allyl-to-alkyl rearrangement of the carbocycle in this sequence and all its binding modes during the re...    »
 
Journal title:
Chemical communications (Cambridge, England) 
Year:
2017 
Journal volume:
53 
Journal issue:
13 
Pages contribution:
2098-2101 
Publisher:
Royal Society of Chemistry (RSC) 
Print-ISSN:
1359-7345 
E-ISSN:
1364-548X