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Document type:
Zeitschriftenaufsatz 
Author(s):
Chen, Lipeng; Gelin, Maxim F.; Chernyak, Vladimir Y.; Domcke, Wolfgang; Zhao, Yang 
Title:
Dissipative dynamics at conical intersections: simulations with the hierarchy equations of motion method 
Abstract:
The effect of a dissipative environment on the ultrafast nonadiabatic dynamics at conical intersections is analyzed for a two-state two-mode model chosen to represent the S2(ππ*)-S1(nπ*) conical intersection in pyrazine (the system) which is bilinearly coupled to infinitely many harmonic oscillators in thermal equilibrium (the bath). The system-bath coupling is modeled by the Drude spectral function. The equation of motion for the reduced density matrix of the system is solved numerically exactl...    »
 
Journal title:
Faraday discussions 
Year:
2016 
Journal volume:
194 
Pages contribution:
61-80 
Fulltext / DOI:
Publisher:
Royal Society of Chemistry (RSC) 
Print-ISSN:
1359-6640 
E-ISSN:
1364-5498