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- Document type:
- Zeitschriftenaufsatz
- Author(s):
- Bentlohner, Manuel M.; Fischer, Christina; Fässler, Thomas F.
- Title:
- Synthesis and characterization of pristine closo-Ge10(2.)
- Abstract:
- The first [Ge10](2-) Zintl anion, which is neither filled nor connected to another metal atom is presented in terms of X-ray structure, Raman-spectrum and ESI-MS. Pure [Ge10](2-), adapting a D4d symmetric closo-structure, were crystallized from a Rb4Ge9/ethylendiamine solution, containing 7-amino-1-trimethylsilyl-5-aza-hepta-3-en-1-yne. The role of the latter on the formation of [Rb(222-crypt)]2[Ge10](en)1.5 is discussed.
- Journal title:
- Chemical communications (Cambridge, England)
- Year:
- 2016
- Journal volume:
- 52
- Journal issue:
- 63
- Pages contribution:
- 9841-9843
- Fulltext / DOI:
- doi:10.1039/c6cc04143d
- Publisher:
- Royal Society of Chemistry (RSC)
- Print-ISSN:
- 1359-7345
- E-ISSN:
- 1364-548X
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