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Dokumenttyp:
Zeitschriftenaufsatz 
Autor(en):
Eckhard, J.F.; Neuwirth, D.; Panosetti, C.; Oberhofer, H.; Reuter, K.; Tschurl, M.; Heiz, U. 
Titel:
Consecutive reactions of small, free tantalum clusters with dioxygen controlled by relaxation dynamics 
Abstract:
The reaction of small cationic tantalum clusters (Tan+, n = 4–8) with molecular oxygen is studied under multi-collision conditions in the gas phase, and the reaction kinetics are analyzed in order to elucidate underlying mechanisms. Reaction pathways as well as relevant apparent rate constants are reported. Two principal pathways in the consecutive oxidation reaction are present in this size regime: solely oxidative degradation (loss of a TaO fragment) in the beginning followed by parallel intac...    »
 
Dewey Dezimalklassifikation:
540 Chemie 
Zeitschriftentitel:
Physical Chemistry Chemical Physics 
Jahr:
2017 
Jahr / Monat:
2017-01 
Heft / Issue:
Seitenangaben Beitrag:
5985-5993 
Verlag / Institution:
Royal Society of Chemistry