Size-dependent gas phase reactivity of tantalum cluster cations with small alcohols

Dokumenttyp:: Zeitschriftenaufsatz
Autor(en):: Lange, K.; Visser, B.; Neuwirth, D.; Eckhard, J.F.; Boesl, U.; Tschurl, M.; Bowen, K.H.; Heiz, U.
Titel:: Size-dependent gas phase reactivity of tantalum cluster cations with small alcohols
Abstract:: Abstract Small tantalum cluster cations (Ta4–9+) were produced in the gas phase by laser vaporization. Various alcohols (methanol, ethanol, n-propanol and 2-propanol) were consecutively added to the cluster beam in a pulsed jet and allowed to react to an extent of conversion of approximately 50
Stichworte:: OH abstraction
Zeitschriftentitel:: International Journal of Mass Spectrometry
Jahr:: 2015
Band / Volume:: 375
Heft / Issue:: 0
Seitenangaben Beitrag:: 9 - 13
Volltext / DOI:: doi:10.1016/j.ijms.2014.10.010
Print-ISSN:: 1387-3806
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