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Author(s):
Judai, K.; Woerz, A. S.; Abbet, S.; Heiz, U. 
Title:
Chemical reactivity of free and supported metal clusters 
Abstract:
A review. Topics covered include: chem. reactions on point defects of oxide surfaces and chem. reactions and catalytic processes on free and supported clusters. Size-selected clusters in the gas-phase and supported on solid surfaces reveal distinct and atom- by atom size-dependent chem. properties, which differ in many ways from those of their bulk analogs. The efficiencies and branching ratios of chem. reactions can be changed by cluster size and the presented examples showed that the cluster's...    »
 
Keywords:
Catalysis Cluster structure Point defects Reactivity Surface (chem. reactivity of free and supported metal clusters) Clusters (metal chem. reactivity of free and supported metal clusters) review chem reactivity free supported metal cluster 
Congress title:
CAN 142:141443 65-0 General Physical Chemistry Institute of Surface Science and Catalysis, University of Ulm, Ulm, Germany. Journal; General Review 
Journal title:
NATO Sci. Ser., II 
Year:
2003 
Journal volume:
116 
Journal issue:
Metal-Ligand Interactions 
Pages contribution:
153-192 
Fulltext / DOI: