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Autor(en):
Bornschlegl, Alexander; Boesl, Ulrich 
Titel:
Circular dichroism laser mass spectrometry of 3-methylcyclopentanone 
Abstract:
For optically active substances the ionization yield for left and right circularly polarized light is different. We present mass resolved multi photon ionization CD (MPI-CD) spectra of (+)- and (-)-3-Methylcyclopentanone (3-MCP) and other carbonyles. The electronically forbidden, but magnetically allowed Ï€*←n-transition of 3-MCP shows a very strong relative CD in ion yield which makes this substance ideally suited for basic investigations. When ionizing 3-MCP with 1+1+1 MPI via the Ï€* state,...    »
 
Kongresstitel:
Chemistry Department/Physical Chemistry 1, Technical University Munich, D-85748 Garching, Germany. Conference; Meeting Abstract; Computer Optical Disk 
Zeitschriftentitel:
Abstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007 
Jahr:
2007 
Seitenangaben Beitrag:
PHYS-260