Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

Voss, F.; Herdtweck, E.; Bach, T.

doi:10.1039/c0cc04636a

Document type:: Journal Article
Author(s):: Voss, F.; Herdtweck, E.; Bach, T.
Title:: Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions
Abstract:: A chiral Mn(salen)complex exhibiting two lactam binding sites at two rigid 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one skeletons is capable of enantioselective sulfoxidation due to spatially remote substrate hydrogen bonding.
Congress title:: ISI Document Delivery No.: 713VX Times Cited: 5 Cited Reference Count: 51 Voss, Felix Herdtweck, Eberhardt Bach, Thorsten Deutsche Forschungsgemeinschaft [Ba 1372-10]; Fonds der Chemischen Industrie This project was supported in part by the Deutsche Forschungsgemeinschaft (Ba 1372-10) and by the Fonds der Chemischen Industrie. 5 Royal soc chemistry Cambridge
Journal title:: Chemical Communications
Year:: 2011
Journal volume:: 47
Journal issue:: 7
Pages contribution:: 2137-2139
Fulltext / DOI:: doi:10.1039/c0cc04636a
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