Bridge functionalized bis-N-heterocyclic carbene rhodium(I) complexes and their application in catalytic hydrosilylation

Straubinger, C. S.; Jokic, N. B.; Hogerl, M. P.; Herdtweck, E.; Herrmann, W. A.; Kuhn, F. E.

doi:10.1016/j.jorganchem.2010.09.049

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Document type:: Journal Article
Author(s):: Straubinger, C. S.; Jokic, N. B.; Hogerl, M. P.; Herdtweck, E.; Herrmann, W. A.; Kuhn, F. E.
Title:: Bridge functionalized bis-N-heterocyclic carbene rhodium(I) complexes and their application in catalytic hydrosilylation
Abstract:: A series of chelating bridge functionalized bis-N-heterocyclic carbenes (NHC) complexes of rhodium (I) were prepared by reacting the corresponding imidazolium salts with [Rh(COD) Cl](2) in an in-situ reaction. For the N-methyl substituted complex with a PF6-anion an X-ray crystal structure was exemplary obtained. All complexes were spectroscopically characterized and tested for the hydrosilylation of acetophenone. (C) 2010 Elsevier B.V. All rights reserved.
Congress title:: ISI Document Delivery No.: 724XC Times Cited: 5 Cited Reference Count: 40 Straubinger, Claudia S. Jokic, Nadezda B. Hoegerl, Manuel P. Herdtweck, Eberhardt Herrmann, Wolfgang A. Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010; Herrmann, Wolfgang/A-3588-2010 Universitat Bayern e. V.; Wacker Insitut fur Silicium Chemie-Wacker AG; International Graduate School of Science and Engineering (IGSSE) We gratefully acknowledge Dr. Monica Carril and Serena L. M. Goh for helpful discussions. This work was supported by Universitat Bayern e. V. (Ph.D. fellowship for N.B.J.) and the Wacker Insitut fur Silicium Chemie-Wacker AG (Ph.D. fellowship for M. P. H). We further thank the International Graduate School of Science and Engineering (IGSSE) for financial support. 5 Elsevier science sa Lausanne «
ISI Document Delivery No.: 724XC Times Cited: 5 Cited Reference Count: 40 Straubinger, Claudia S. Jokic, Nadezda B. Hoegerl, Manuel P. Herdtweck, Eberhardt Herrmann, Wolfgang A. Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010; Herrmann, Wolfgang/A-3588-2010 Universitat Bayern e. V.; Wacker Insitut fur Silicium Chemie-Wacker AG; International Graduate School of Science and Engineering (IGSSE) We gratefully acknowledge Dr. Monica Carril and Serena L. M. Goh for helpful discussions. This work was suppor... »
Journal title:: Journal of Organometallic Chemistry
Year:: 2011
Journal volume:: 696
Journal issue:: 3
Pages contribution:: 687-692
Fulltext / DOI:: doi:10.1016/j.jorganchem.2010.09.049
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