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Journal Article 
Straubinger, C. S.; Jokic, N. B.; Hogerl, M. P.; Herdtweck, E.; Herrmann, W. A.; Kuhn, F. E. 
Bridge functionalized bis-N-heterocyclic carbene rhodium(I) complexes and their application in catalytic hydrosilylation 
A series of chelating bridge functionalized bis-N-heterocyclic carbenes (NHC) complexes of rhodium (I) were prepared by reacting the corresponding imidazolium salts with [Rh(COD) Cl](2) in an in-situ reaction. For the N-methyl substituted complex with a PF6-anion an X-ray crystal structure was exemplary obtained. All complexes were spectroscopically characterized and tested for the hydrosilylation of acetophenone. (C) 2010 Elsevier B.V. All rights reserved. 
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ISI Document Delivery No.: 724XC Times Cited: 5 Cited Reference Count: 40 Straubinger, Claudia S. Jokic, Nadezda B. Hoegerl, Manuel P. Herdtweck, Eberhardt Herrmann, Wolfgang A. Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010; Herrmann, Wolfgang/A-3588-2010 Universitat Bayern e. V.; Wacker Insitut fur Silicium Chemie-Wacker AG; International Graduate School of Science and Engineering (IGSSE) We gratefully acknowledge Dr. Monica Carril and Serena L. M. Goh for helpful discussions. This work was suppor...    »
Journal title:
Journal of Organometallic Chemistry 
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