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Dokumenttyp:
Journal Article 
Autor(en):
Jokic, N. B.; Zhang-Presse, M.; Goh, S. L. M.; Straubinger, C. S.; Bechlars, B.; Herrmann, W. A.; Kuhn, F. E. 
Titel:
Symmetrically bridged bis-N-heterocyclic carbene rhodium (I) complexes and their catalytic application for transfer hydrogenation reaction 
Abstract:
Bridged rhodium(I) bis(NHC) complexes of the formula [bis-(NHC)Rh(I)PF6] (1c-5c) were synthesized and applied as catalysts in the transfer hydrogenation of acetophenone in 2-propanol. The activity of the rhodium(I) complexes largely depends on the nature of the N-substituents and the applied bases. The synthesized compounds were characterized by elemental analysis, H-1 and C-13 NMR-spectroscopy and mass spectrometry. The structure of complex 2c was exemplary determined by X-ray analysis. (C) 201...    »
 
Kongresstitel:
ISI Document Delivery No.: 842AL Times Cited: 6 Cited Reference Count: 50 Jokic, Nadezda B. Zhang-Presse, Mei Goh, Serena L. M. Straubinger, Claudia S. Bechlars, Bettina Herrmann, Wolfgang A. Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010; Herrmann, Wolfgang/A-3588-2010 Bayerische Forschungsstiftung; Universitat Bayern e. V.; The International Graduate School of Science and Engineering (IGSSE); TUM Graduate School Universitat Bayern e. V. is acknowledged for a Ph.D. fellowship for N.B.J., S.L.M.G....    »
 
Zeitschriftentitel:
Journal of Organometallic Chemistry 
Jahr:
2011 
Band / Volume:
696 
Heft / Issue:
24 
Seitenangaben Beitrag:
3900-3905